Structure of the allyl group In organic chemistry an allyl group is a substituent with the structural formula H2C=CH−CH2R where R is the rest of the molecule It consists of a methylene bridge −CH2− attached to a vinyl group −CH=CH2 [1] [2] The name is derived from the Latin word for garlic Allium sativum
Get PriceXANTHATES are salts or esters of xanthic acid C2H5OC =S SH but the term also applies to salts or esters of any acid of the structure ROC =S SH where R is an alkyl or similar radical Xanthates are generally yellowish solids with pungent odors Generally soluble in water
Get PriceThe xanthate esters are of interest in that if the O alkyl group contains at least one a hydrogen atom pyrolysis produces an olefin a thiol and carbon oxysul phide the Chugaev reaction Section p 489 [] Isolation of the intermediate xanthate salts in the preparation of the xanthate esters is not essential
Get PriceJan 20 2022Sodium Ethyl Xanthate SEX Sodium Ethyl Xanthate can be in the form of a yellowish pellet or powdered form It is a sodium salt form of C2 alkyl ethyl alcohol The chemical is highly soluble in water This Xanthate is known to be the strongest among Xanthates and a highly selective collector The functions of Sodium Ethyl Xanthate are It is a
Get PriceProducts Tionocarbamato Matcol D 101 Mathiesen NP 107 Clariant AERO 3894 PROMOTER Base Xantoformiato Colector de cobre Dialquil Xantoformiato Aero 3758 Promoter ex SF 758 Hostaflot P 24 Z 11 AERO 343 XANTHATE AERO 317 XANTHATE SF 113 XANTATO RENASA XANTATO SF 926 Z 9 Z 3 Z 4 Z 7 Z 14 Z 6 SF 114 Z 200 MINEREC1661 HOSTAFLOT X 23
Get PriceIt is well known that xanthates are the most commonly used collectors in the flotation of sulfide and some oxidized ores Amrollahi et al 2024 However several investigations have shown
Get Pricexanthates alkyl or aryl derivatives of dithiocarbonic acid have been shown to be selective mechanism based inactivators of cytochromes p450 2b1/2b6 and 2e1 due to covalent binding of a reactive intermediate to apoprotein after double hydrogen abstraction at α carbon atom suggesting interaction of the xanthate dithiocarbonic head with the …
Get PriceThe impact of pH and copper activation on adsorption of xanthate on pyrite was also investigated It was found that at low pH dixanthogen is the dominant species of xanthate adsorption on pyrite At high pH metal xanthate complexes were found to be prevalent on pyrite surfaces which are responsible for the surface hydrophobicity
Get PriceXanthates are water soluble powders or pellets usually with a strong and unpleasant odour and they are usually applied as 10 to 20% solutions Their water solubilities vary from 110 to 460 g/L and increase at higher temperatures Cyanamid 1989 They would not be expected to enter the environment in normal well run mining operations but may
Get PriceJan 30 2022Sodium Ethyl Xanthate SEX Sodium Ethyl Xanthate can be in the form of a yellowish pellet or powdered form It is a sodium salt form of C2 alkyl ethyl alcohol The chemical is highly soluble in water This Xanthate is known to be the strongest among Xanthates and a highly selective collector The functions of Sodium Ethyl Xanthate are
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Get PriceClariant an innovative speciality chemicals company is responding to these challenges by rolling out speciality solutions in copper platinum and gold base metal mining sectors with the implementation of safer better alternatives to xanthate collectors The company has introduced and tested HOSTAFLOT 7800 as a Xanthate Replacement collector
Get PriceA novel fluoro xanthate 2 4 fluorophenoxycarbonothioyl thio ethyl propanoate was developed and successfully used as a mediator in the photoinduced controlled radical polymerization of more activated monomers methyl acrylate MA butyl acrylate and N isopropylacrylamide and a less activated monomer vinyl acetate VAc
Get PriceFeb 4 2021In this paper we describe a metal xanthate precursor route to produce ternary silver antimony sulfide AgSbS 2 as a single well defined phase via thermal decomposition of metal
Get PriceThe present invention relates to a method for preparing an aqueous dispersion of water soluble polymers which comprises a step E of radical polymerization wherein the following are brought into contact in an aqueous medium M in which the synthesized polymer is not soluble at least one ethylenically unsaturated monomer which is soluble in the aqueous medium M at least one source of
Get Pricexanthate any of a class of organic salts formed by treatment of an alcohol with carbon disulfide in the presence of an alkali The term is derived from the Greek word xanthos for yellow in reference to the compound potassium ethyl xanthate C 2 H 5 OCS 2 K which gives a yellow precipitate when combined with copper sulfate
Get PriceThe flotation chemistry between pyrite and isomeric xanthates butyl xanthate and isobutyl xanthate was investigated by means of adsorption experiments surface tension tests and molecular dynamic simulations in this work The flotation chemical results were confirmed and further interpreted by quantum chemical calculations The experiment results demonstrated that the isobutyl xanthate
Get PricePotassium amylxanthate C6H11KOS2 CID 493949 structure chemical names physical and chemical properties classification patents literature biological
Get PricePOTASSIUM ETHYL XANTHATE Extra Pure Safety Data Sheet 09/04/2024 2/10 Classification according to Directive 67/548/EEC or 1999/45/EC Xn R22 Xi R36/37/38 Full text of R phrases see section 16 Adverse physicochemical human health and environmental effects No additional information available Label elements
Get PriceIdentified health effects NICNAS Sodium Ethyl Xanthate May 1995 include irritation to eyes skin and respiratory tract acute poisoning effects including tremor prostration dyspnea cyanosis and vascular collapse psychosis or narcosis may result from acute levels of up 500 1000ppm Long term exposure at high levels are responsible for
Get PriceNov 9 2020This study demonstrates the effects of a potassium propyl xanthate PPX collector and sodium sulfite Na 2 SO 3 depressant on pure chalcopyrite in synthetic seawater SSW and potassium chloride KCl solutions SSW solutions with 35 g/L of salt and M KCl were used for microflotation and zeta potential tests
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Get PriceSodium/potassium Ethyl Xanthate Sodium/potassium Isopropyl Xanthate Sodium/potassium Butyl Xanthate Sodium/potassium Isobutyl Xanthate Sodium/Potassium Amyl Xanthate dithiocarbamate ES SN 9 # Sodium Diethyl Dithiophosphate Sodium Iso n sec butyl dithiophosphate Dithiophosphate 25 Dithiophosphate 25s Dithioposphate 31 Ammonium Dibutyl
Get PriceIt can be explained as follows when the concentrations of metal ions were low the amounts of metal ions were far lower than the saturated adsorption capacity of cross linked starch xanthate The polymeric absorbent has many vacant sites so the concentration gradient took place in the solution that it can constantly absorb Pb 2 and Cd 2
Get PriceApr 6 2022The poly lactide co xanthate copolymers show enhanced UV degradability compared to PLA with 40% mass loss within 6 hours of UV exposure 365 nm for only 3% of sulfur containing linkages This article is part of the themed collections Chemical Communications HOT Articles 2024 and 2024 Pioneering Investigators
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Get PriceE DOI / Org Lett XXXX XXX XXX−XXX Organic Letters Letter w Vara B A Patel N R Molander G A O Benzyl Xanthate benzotriazole 5 carboxylic Acid CBt PMN by Direct [11C]Carbon Esters under Ni/Photoredox Dual Catalysis Selective Radical Dioxide Fixation via Organolithiation of Trialkyltin Precursor and Generation and Csp3 Csp2 Cross Coupling
Get PriceXanthates produce carbon disulfide in an aqueous solution through dissociation and through hydrolysis Dissociation is more important in acidic media while hydrolysis prevails in alkaline solutions and is the main reaction pathway in mining processes Commonwealth of Australia 1995
Get Pricec The conversion of xanthate ester 6 to lactam 7 by treating 6 with a radical initiator in the presence of ethyl allyl sulfone [hint the byproducts are SO 2 ethane and EtS C=S OEt ] d The thiamine catalyzed formation of benzoin 9 from the substituted benzaldehyde derivative 8
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